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artículo con referato
"Synthesis of a Phenanthridine Analogue of Natural Isocarbostyril Alkaloids"
A.R. Martinez, D. Vega, J.M. Aguirre, B. Lantaño and G.Y. Moltrasio
Synthesis 2012(1) (2012) 125-129
Abstract
A phenanthridine alkaloid analogue has been synthesized by a short sequence, using a stereoselective hydroxylation process and a Pictet.Spengler reaction. The starting material, 5-(3,4-dimethoxyphenyl)-6-nitrocyclohex-2-enol, is a compound previously reported by us and prepared through a Diels.Alder reaction. The configurational assignment of the starting material, previously done by NMR experiments, was confirmed by X-ray crystallographic analysis.
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