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Inicio » Actividades I+D > Publicaciones 2006 > Aqua(thiosulfato-κ2O,S)[2,4,6-tri-2-pyri...
artículo con referato
"Aqua(thiosulfato-κ2O,S)[2,4,6-tri-2-pyridyl-1,3,5-triazine-κ3N2,N1,N6]zinc(II) hemihydrate"
M.E. Díaz de Vivar, S. Baggio and R. Baggio
Acta Cryst. C 62(5) (2006) m192-m194
Abstract
The title compound, [Zn(S2O3)(C18H12N6)(H2O)]·0.5H2O, contains two almost identical independent monomeric moieties composed of an octahedral Zn centre coordinated by a tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine (tpt) ligand, one aqua ligand and an O,S-chelating thiosulfate anion. The structure is stabilized by a solvent water molecule. Multiple strong hydrogen bonds with additional weaker ππ interactions between tpt groups define a multiple column spatial organization.
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