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Inicio » Actividades I+D > Publicaciones 2013 > Dimers linked by type-I C-F⋯F-C contacts...
artículo con referato
"Dimers linked by type-I C-FF-C contacts in (Z)-3-methyl-4-[2-(4-methylphenyl)hydrazinylidene]-1-(pentafluorophenyl)-1H-pyrazol-5(4H)-one"
Luis Alvarez-Thon, Carlos Bustos, Katherina Espinoza-Santibañez, María Teresa Garland and Ricardo Baggio
Acta Cryst. C 69(10) (2013) 1200-1204
Abstract
The title compound, C17H11F5N4O, is described and compared with two closely related analogues in the literature. There are two independent molecules in the asymmetric unit, linked by N–HO hydrogen bonds and ππ interactions into dimeric entities, presenting a noticeable noncrystallographic C2 symmetry. These dimers are in turn linked by a medium-strength type-I C–FF–C interaction into elongated tetramers. Much weaker C–HF contacts link the tetramers into broad two-dimensional substructures parallel to (101).
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