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Inicio » Actividades I+D > Publicaciones 2002 > Bis(1,10-phenanthroline)(thiosulfato)man...
artículo con referato
"Bis(1,10-phenanthroline)(thiosulfato)manganese(II) methanol solvate and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline)manganese(II)]-μ-thiosulfato]"
E. Freire, S. Baggio, J.C. Muñoz and R. Baggio
Acta Cryst. C 58(8) (2002) m455-m458
Abstract
The structure of bis(1,10-phenanthroline-κ2N,N′)(thiosulfato-κ2O:S)manganese(II) methanol solvate, [Mn(S2O3)(C12H8N2)2]·CH3OH, is made up of Mn2+ centers coordinated to two bidentate phenanthroline (phen) groups and an S,O-chelating thiosulfate anion, forming monomeric entities. The structure of catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)manganese(II)]-μ-thiosulfato-κ2O:S], [Mn(S2O3)(C14H12N2)(H2O)2]n, is polymeric, consisting of Mn(dmph)(H2O)2 units (dmph is 2,9-dimethyl-1,10-phenanthroline) linked by thiosulfate anions acting in an S,O-chelating manner.
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